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The 2025 college football season kicked off Saturday with a top 25 matchup in Week 0. No. 21 Iowa State defeated No. 20 Kansas State, 24-21, in Dublin, Ireland. Rankings reflect the US LBM Coaches Poll.
Four other FBS games were contested on Saturday.
UNLV defeated Idaho State, 38-31, at Allegiant Stadium in Las Vegas, Nevada, while Kansas was victorious at home versus Fresno State, 31-7.
Former Tennessee offensive coordinator and seventh-year head coach Tyson Helton guided Western Kentucky to a, 41-24, home win versus Sam Houston.
Hawaii won the final Week 0 contest, defeating Stanford, 23-20, in Honolulu, Hawaii.
No. 18 Tennessee will open its season in Week 1 versus Syracuse in Atlanta, Georgia. Following Week 0 contests, ESPN Football Power Index released updated win percentage chances for each game in 2025.
ESPN FPI projects the Vols to have an 88.6 percent chance to defeat Syracuse. Below are win percentage chances for the Vols in regular-season games from ESPN FPI after Week 0.
Syracuse Orange
Prediction: Tennessee 88.6 percent chance to win
Location: Mercedes-Benz Stadium (Atlanta, Georgia)
Date: Aug. 30
East Tennessee State Buccaneers
Prediction: Tennessee 99.0 percent chance to win
Location: Neyland Stadium (Knoxville, Tennessee)
Date: Sept. 6
Georgia Bulldogs
Prediction: Georgia 59.3 percent chance to win
Location: Neyland Stadium (Knoxville, Tennessee)
Date: Sept. 13
UAB Blazers
Prediction: Tennessee 98.1 percent chance to win
Location: Neyland Stadium (Knoxville, Tennessee)
Date: Sept. 20
Mississippi State Bulldogs
Prediction: Tennessee 80.3 percent chance to win
Location: Davis Wade Stadium (Starkville, Mississippi)
Date: Sept. 27
Arkansas Razorbacks
Prediction: Tennessee 76.6 percent chance to win
Location: Neyland Stadium (Knoxville, Tennessee)
Date: Oct. 11
Alabama Crimson Tide
Prediction: Alabama 68.4 percent chance to win
Location: Bryant-Denny Stadium (Tuscaloosa, Alabama)
Date: Oct. 18
Kentucky Wildcats
Prediction: Tennessee 74.8 percent chance to win
Location: Kroger Field (Lexington, Kentucky)
Date: Oct. 25
Oklahoma Sooners
Prediction: Tennessee 73.7 percent chance to win
Location: Neyland Stadium (Knoxville, Tennessee)
Date: Nov. 1
New Mexico State Aggies
Prediction: Tennessee 99.0 percent chance to win
Location: Neyland Stadium (Knoxville, Tennessee)
Date: Nov. 15
Florida Gators
Prediction: Florida 51.5 percent chance to win
Location: Ben Hill Griffin Stadium (Gainesville, Florida)
Date: Nov. 22
Vanderbilt Commodores
Prediction: Tennessee 85.2 percent chance to win
Location: Neyland Stadium (Knoxville, Tennessee)
Date: Nov. 29
Tennessee will have an open date on Oct. 4 and Nov. 8.
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